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PhysicsFan Apr 20, 2026 • 10 views

AP Chemistry Multiple Choice Questions on Molecular Geometry and Hybridization

Hey everyone! 👋 Let's tackle molecular geometry and hybridization in AP Chemistry! This stuff can be tricky, but with a good review and some practice, you'll be rocking it in no time. Here's a quick study guide and a quiz to help you master these concepts. Good luck!🍀
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⚛️ Quick Study Guide

  • 📐 VSEPR Theory: Valence Shell Electron Pair Repulsion theory predicts molecular geometry based on minimizing electron pair repulsion around a central atom.
  • ✍️ AXE Notation: Use $AX_mE_n$ to represent molecules, where A is the central atom, X is the number of bonded atoms, and E is the number of lone pairs.
  • Common Geometries:
    • Linear: $AX_2$ (e.g., $CO_2$)
    • Trigonal Planar: $AX_3$ (e.g., $BF_3$)
    • Tetrahedral: $AX_4$ (e.g., $CH_4$)
    • Trigonal Pyramidal: $AX_3E$ (e.g., $NH_3$)
    • Bent: $AX_2E_2$ (e.g., $H_2O$)
  • 🧪 Hybridization: Describes the mixing of atomic orbitals to form new hybrid orbitals for bonding.
    • $sp$: Linear
    • $sp^2$: Trigonal Planar
    • $sp^3$: Tetrahedral
    • $sp^3d$: Trigonal Bipyramidal
    • $sp^3d^2$: Octahedral
  • Sigma ($\sigma$) and Pi ($\pi$) Bonds: Single bonds are $\sigma$ bonds. Double bonds consist of one $\sigma$ and one $\pi$ bond. Triple bonds consist of one $\sigma$ and two $\pi$ bonds.
  • 💡 Tips: Draw Lewis structures first! Then, determine the AXE notation to predict geometry and hybridization.

🧪 Practice Quiz

  1. Which of the following molecules has a tetrahedral molecular geometry?
    1. $BF_3$
    2. $CO_2$
    3. $CH_4$
    4. $H_2O$
  2. What is the hybridization of the central atom in $SF_6$?
    1. $sp^3$
    2. $sp^3d$
    3. $sp^3d^2$
    4. $sp^2$
  3. Which of the following molecules is linear?
    1. $H_2O$
    2. $NH_3$
    3. $CO_2$
    4. $SO_2$
  4. What is the molecular geometry of $NH_3$?
    1. Tetrahedral
    2. Trigonal Planar
    3. Trigonal Pyramidal
    4. Bent
  5. How many sigma ($\sigma$) and pi ($\pi$) bonds are in a molecule of $C_2H_2$?
    1. 2 $\sigma$ and 2 $\pi$
    2. 3 $\sigma$ and 2 $\pi$
    3. 3 $\sigma$ and 3 $\pi$
    4. 5 $\sigma$ and 0 $\pi$
  6. What is the bond angle in a molecule with trigonal planar geometry?
    1. 90°
    2. 109.5°
    3. 120°
    4. 180°
  7. Which of the following molecules has a bent molecular geometry?
    1. $BeCl_2$
    2. $CO_2$
    3. $H_2S$
    4. $BF_3$
Click to see Answers
  1. C
  2. C
  3. C
  4. C
  5. B
  6. C
  7. C

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