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anita_wallace Feb 13, 2026 • 0 views

Difference Between Bronsted-Lowry Acid and Lewis Acid

Hey there, chemistry students! 👋 Ever get tripped up trying to explain the difference between Brønsted-Lowry acids and Lewis acids? 🤔 It's a common sticking point, but once you understand the core concepts, it becomes much easier. Let's break it down!
🧪 Chemistry

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📚 Understanding Brønsted-Lowry Acids

A Brønsted-Lowry acid is defined as a proton (H⁺) donor. In simpler terms, it's a substance that gives away a hydrogen ion to another substance during a chemical reaction. Think of it as passing the hydrogen 'hot potato'.

  • ⚛️ Key Concept: Proton Donation
  • 📝 Example: $HCl(aq) + H_2O(l) \rightleftharpoons H_3O^+(aq) + Cl^-(aq)$. Here, $HCl$ is the Brønsted-Lowry acid donating a proton to water.
  • 🧪 Implication: Requires the presence of a removable proton.

⚛️ Understanding Lewis Acids

A Lewis acid, on the other hand, is defined as an electron pair acceptor. It's a substance that can accept a pair of electrons to form a covalent bond. This definition broadens the scope of what can be considered an acid beyond just proton donors.

  • ⚡️ Key Concept: Electron Pair Acceptance
  • 🧪 Example: $BF_3 + NH_3 \rightarrow BF_3NH_3$. $BF_3$ acts as a Lewis acid by accepting an electron pair from $NH_3$.
  • 💡 Implication: Doesn't necessarily need to contain hydrogen.

🧪 Brønsted-Lowry vs. Lewis Acids: A Detailed Comparison

Feature Brønsted-Lowry Acid Lewis Acid
Definition Proton (H⁺) donor Electron pair acceptor
Key Action Donates a proton Accepts an electron pair
Hydrogen Requirement Must contain removable H⁺ Not required to contain hydrogen
Examples $HCl, H_2SO_4, CH_3COOH$ $BF_3, AlCl_3, Ag^+$
Scope More limited; focuses on proton transfer Broader; includes substances without protons

🔑 Key Takeaways

  • 🧠 The Brønsted-Lowry definition focuses on proton ($H^+$) donation, while the Lewis definition focuses on electron pair acceptance.
  • 💡 All Brønsted-Lowry acids are also Lewis acids, but not all Lewis acids are Brønsted-Lowry acids. The Lewis definition is more encompassing.
  • ⚗️ Understanding both definitions is crucial for grasping acid-base chemistry in various contexts.

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